CHEM 2414 Organic & Biochemistry Name: ____________________

 

Chapter 12 Part L: Chapter 12 End of Chapter Exercises    16 points

 

Question #1: p 359-360 Alkenes and Alkynes: Questions  12.21-12.30

 

12.25 Of the following compounds, which can exist as cis-trans geometric Isomers. Draw the two geometric isomers for those that can exists.

 

a.    2,3 Dibromo butane                                                b.    2-Heptene

 

 

 

 

 

c.    2,3 Dibromo-2-butene                                             d.     propene

 

 

 

 

e.    1-Bromo-1Chloro-2-methylpropene                     f.     1,1-Dichloroethene

 

 

 

 

g.  1,2-Dibromoethene                                             h.     3-Ethyl-2-methyl-2-hexene

 

 

 

 

 

 

Question #2 p 360-361 Reactions Involving Alkenes: Questions 12.31-12.48

12.34 Draw and name the product in each of the

 

 Cyclopentene  + HOH  (H+)  à                                                     

 

 

 

 

Cyclopentene  +   HCl       à                                                           

 

 

 

Cyclopentene + H2   à

 

 

 

Cyclopentene  +  HI  à

 

 

 

Question #3 p 361-362 Aromatic Hydrocarbons: Questions 12.49-12.58

12.49 Draw the structure for each of the following compounds:

 

a.       2,4 Dibromotoluene

   

 

 

 

 

 

b.      1,2,4 Trimethylbenzene

 

 

 

 

 

 

     c.    isopropylbenzene

 

 

 

 

 

     d. 2-Bromo-5chlorotoluene

 

 

 

 

 

Bonus: Benzoic Acid

 

 

 

 

 

 

Bonus: Analine

 

 

 

 

Bonus:  Phenol